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Nylon Info

Nylon

From Wikipedia, the free encyclopedia

For other uses of this word, see nylon (disambiguation).

Nylon

Density 1.15 g/cm³

Electrical conductivity (σ) 10-12 S/m

Thermal conductivity 0.25 W/(m·K)

Melting point 463 K-624 K

190°C-350°C

374°F-663°F

Nylon is a generic designation for a family of synthetic polymers first produced on February 28, 1935 by Wallace Carothers at DuPont.

Contents

1 Overview

2 Chemistry

3 Nylon Fiber

3.1 Basic Concepts of Nylon Production

4 Bulk properties

5 Historical uses

6 Etymology

7 Uses

8 See also

9 References

10 External links

Overview

Nylon is a thermoplastic material, first used commercially in a nylon-bristled toothbrush (1938), followed more famously by women's “nylons” stockings (1940). It is made of repeating units linked by peptide bonds (another name for amide bonds) and is frequently referred to as polyamide (PA). Nylon was the first commercially successful polymer and the first synthetic fiber to be made entirely from coal, water and air. These are formed into monomers of intermediate molecular weight, which are then reacted to form long polymer chains. It was intended to be a synthetic replacement for silk and substituted for it in parachutes and also making things like ropes, flak vests, vehicle tires, combat uniforms and many other military uses after the United States entered World War II in 1941, making stockings hard to find until the war's end. Nylon fibers are now used in fabrics, bridal veils, carpets, guitar strings and ropes, and solid nylon is used for mechanical parts, drumstick tips and as an engineering material. Engineering grade Nylon is processed by extrusion, casting & injection molding. Type 6/6 Nylon 101 is the most common commercial grade of Nylon, and Nylon 6 is the most common commercial grade of cast Nylon.

Chemistry

Nylons are condensation copolymers formed by reacting equal parts of a diamine and a dicarboxylic acid, so that peptide bonds form at both ends of each monomer in a process analogous to polypeptide biopolymers. The numerical suffix specifies the numbers of carbons donated by the monomers; the diamine first and the diacid second. The most common variant is nylon 6-6 which refers to the fact that the diamine (hexamethylene diamine) and the diacid (adipic acid) each donate 6 carbons to the polymer chain. As with other regular copolymers like polyesters and polyurethanes, the "repeating unit" consists of one of each monomer, so that they alternate in the chain. Since each monomer in this copolymer has the same reactive group on both ends, the direction of the amide bond reverses between each monomer, unlike natural polyamide proteins which have overall directionality: C terminal → N terminal. In the laboratory, nylon 6,6 can also be made using adipoyl chloride instead of adipic acid.

It is difficult to get the proportions exactly correct, and deviations can lead to chain termination at molecular weights less than a desirable 10,000 daltons (u). To overcome this problem, a crystalline, solid "nylon salt" can be formed at room temperature, using an exact 1:1 ratio of the acid and the base to neutralize each other. Heated to 285 °C, the salt reacts to form nylon polymer. Above 20,000 daltons, it is impossible to spin the chains into yarn, so to combat this, some acetic acid is added to react with a free amine end group during polymer elongation to limit the molecular weight. In practice, and especially for 6,6, the monomers are often combined in a water solution. The water used to make the solution is evaporated under controlled conditions, and the increasing concentration of "salt" is polymerized to the final molecular weight.

DuPont patented[1] nylon 6,6, so in order to compete, other companies (particularly the German BASF) developed the homopolymer nylon 6, or polycaprolactam — not a condensation polymer, but formed by a ring-opening polymerization (alternatively made by polymerizing aminocaproic acid). The peptide bond within the caprolactam is broken with the exposed active groups on each side being incorporated into two new bonds as the monomer becomes part of the polymer backbone. In this case, all amide bonds lie in the same direction, but the properties of nylon 6 are sometimes indistinguishable from those of nylon 6,6 — except for melt temperature (N6 is lower) and some fiber properties in products like carpets and textiles. There is also nylon 9.

Nylon 5,10, made from pentamethylene diamine and sebacic acid, was studied by Carothers even before nylon 6,6 and has superior properties, but is more expensive to make. In keeping with this naming convention, "nylon 6,12" (N-6,12) or "PA-6,12" is a copolymer of a 6C diamine and a 12C diacid. Similarly for N-5,10 N-6,11; N-10,12, etc. Other nylons include copolymerized dicarboxylic acid/diamine products that are not based upon the monomers listed above. For example, some aromatic nylons are polymerized with the addition of diacids like terephthalic acid (→ Kevlar) or isophthalic acid (→ Nomex), more commonly associated with polyesters. There are copolymers of N-6,6/N6; copolymers of N-6,6/N-6/N-12; and others. Because of the way polyamides are formed, nylon would seem to be limited to unbranched, straight chains. But "star" branched nylon can be produced by the condensation of dicarboxylic acids with polyamines having three or more amino groups.

The general reaction is:

A molecule of water is given off and the nylon is formed. Its properties are determined by the R and R' groups in the monomers. In nylon 6,6, R' = 6C and R = 4C alkanes, but one also has to include the two carboxyl carbons in the diacid to get the number it donates to the chain. In Kevlar, both R and R' are benzene rings.

Nylon Fiber

The Federal Trade Commissions' Definition for Nylon Fiber: A manufactured fiber in which the fiber forming substance is a long-chain synthetic polyamide in which less than 85% of the amide-linkages are attached directly (-CO-NH-) to two aliphatic groups.

A synthetic thermoplastic fiber. (Nylon melts/glazes easily at relatively low temperatures).

Round, smooth, and shiny filament fibers

cross sections can be either

trilobal to imitate silk

multilobal to increase staple like appearance and hand

It's most widely used structures are multifilament, monofilament, staple or tow and is available as partially drawn or as finished filaments.

Regular nylon has a round cross section and is perfectly uniform. The filaments are generally completely transparent unless they have been delustered or solution dyed. Thus, they are microscopically recognized as glass rods.

Molecular chains of nylon are long and straight variations but have no side chains or linkages.

Cold drawing (step 18 on the model) can align the chains so they are oriented with the lengthwise direction and are highly crystalline.

Nylon is related chemically to the protein fibers silk and wool.

They both have similar dye sites but nylon has many fewer dye sites than wool.

Basic Concepts of Nylon Production

The first approach: combining molecules with an acid (COOH) group on each end are reacted with two chemicals that contain amine(NH2)groups on each end.

This process creates nylon 6,6, made of hexamethylene diamine with six carbon atoms and acidipic acid, as well as six carbon atoms.

The second approach: a compound has an acid at one end and an amine at the other and is polymerized to for a chain with repeating units of(-NH-[CH2]n-CO-)x.

In other words, nylon 6 is made from a single six-carbon substance called caprolactam.

In this equation, if n=5, then nylon 6 is the assigned name. (may also be referred to as polymer)

Nylon 6,6

Pleats and creases can be heat-set at higher temperatures

Difficult to dye

Nylon 6

Better dye Affinity

Softer Hand

Greater elasticity and elastic recovery

Better weathering properties; better sunlight resistance

Full Nylon Production Model

Producers The producers of nylon include: Honeywell Nylon Inc., Invista, Wellman Inc. among many others. The Dupont Company, is the most famous pioneer of the nylon we know today. The companies above now produce the nylon used in our everyday lives.

Trademarks

Variation of luster: nylon has the ability to be vary lusterous, semilusterous or dull.

Durability: it's high tenacity fibers are used for seatbelts, tire cords, ballistic cloth and other uses.

High elongation

Excellent abrasion resistance

Highly resilient (nylon fabrics are heat-set)

Nylon paved the way for easy-care garments

High resistance:

insects and fungi

molds, mildew, rot

many chemicals

Single most important use of Nylon is in carpets

Bulk properties

Above their melting temperatures, Tm, thermoplastics like nylon are amorphous solids or viscous fluids in which the chains approximate random coils. Below Tm, amorphous regions alternate with regions which are lamellar crystals.[1] The amorphous regions contribute elasticity and the crystalline regions contribute strength and rigidity. The planar amide (-CO-NH-) groups are very polar, so nylon forms multiple hydrogen bonds among adjacent strands. Because the nylon backbone is so regular and symmetrical, especially if all the amide bonds are in the trans configuration, nylons often have high crystallinity and make excellent fibers. The amount of crystallinity depends on the details of formation, as well as on the kind of nylon. Apparently it can never be quenched from a melt as a completely amorphous solid.

Nylon 6,6 can have multiple parallel strands aligned with their neighboring peptide bonds at coordinated separations of exactly 6 and 4 carbons for considerable lengths, so the carbonyl oxygens and amide hydrogens can line up to form interchain hydrogen bonds repeatedly, without interruption. Nylon 5,10 can have coordinated runs of 5 and 8 carbons. Thus parallel (but not antiparallel) strands can participate in extended, unbroken, multi-chain β-pleated sheets, a strong and tough supermolecular structure similar to that found in natural silk fibroin and the β-keratins in feathers. (Proteins have only an amino acid α-carbon separating sequential -CO-NH- groups.) Nylon 6 will form uninterrupted H-bonded sheets with mixed directionalities, but the β-sheet wrinkling is somewhat different. The three-dimensional disposition of each alkane hydrocarbon chain depends on rotations about the 109.47° tetrahedral bonds of singly-bonded carbon atoms.

When extruded into fibers through pores in an industrial spinneret, the individual polymer chains tend to align because of viscous flow. If subjected to cold drawing afterwards, the fibers align further, increasing their crystallinity, and the material acquires additional tensile strength.[2] In practice, nylon fibers are most often drawn using heated rolls at high speeds.

Block nylon tends to be less crystalline, except near the surfaces due to shearing stresses during formation. Nylon is clear and colorless, or milky, but is easily dyed. Multistranded nylon cord and rope is slippery and tends to unravel. The ends can be melted and fused with a heat source such as a flame or electrode to prevent this.

There are carbon fiber/nylon composities with higher density than pure nylon.

When dry, polyamide is a good electrical insulator. However, polyamide is hygroscopic. The absorption of water will change some of the material's properties such as its electrical resistance. Nylon is less absorbant than wool or cotton.

Historical uses

Bill Pittendreigh, DuPont, and other individuals and corporations worked diligently during the first few months of World War II to find a way to replace Asian silk with nylon in parachutes. It was also used to make tires, tents, ropes, ponchos, and other military supplies. It was even used in the production of a high-grade paper for U.S. currency. At the outset of the war, cotton accounted for more than 80% of all fibers used, and manufactured and wool fibers accounted for the remaining 20%. By August 1945, manufactured fibers had taken a market share of 25% and cotton had dropped.

Some of the terpolymers based upon nylon are used every day in packaging. Nylon has been used for meat wrappings and sausage sheaths.

Some people, such as Jack Herer, surmise that Cannabis sativa was made illegal because the fibers from the hemp plant, used for fabrics and ropes, were in strong competition with nylon (along with paper, fuel, and other industries). While the production of rope from hemp requires no chemicals or industrial processes, nylon fiber is more than twice as strong as hemp and weighs 25% less. An additional problem is that hemp rope rots from the inside out, making it difficult to determine the condition of a rope at a glance. While hemp was originally used in climbing, this is no longer the case, even in countries where cannabis is legal.

Etymology

In 1940 John W. Eckelberry of DuPont stated that the letters "nyl" were arbitrary and the "on" was copied from the suffixes of other fibers such as cotton and rayon. A later publication by DuPont (Context, vol. 7, no. 2, 1978) explained that the name was originally intended to be "No-Run" ("run" meaning "unravel"), but was modified to avoid making such an unjustified claim and to make the word sound better. The story goes that Carothers changed one letter at a time until DuPont's management was satisfied. But he was not involved in the nylon project during the last year of his life, and committed suicide before the name was coined.

Two theories about the origin of the name claim that it is an acronym of "Now you've lost, Old Nippon" (N.Y.L.O.N.), or that it stands for "New York-London". In the latter case, it is claimed that these were the two cities where the product was researched and developed, or that the inspiration came from a New York to London airplane ticket. There is no evidence for the 'airline ticket' theory, though some compelling evidence of the latter from contemporary researchers at Oxford University who assisted in development...Oxford can be viewed as London from New York, but Nylox would have been more accurate.

Uses

carpet fiber

clothing

fishing lines

footwear

nylon fiber

pantyhose

toothbrush bristles

velcro

airbag fiber

pants

auto parts: intake manifolds, gas (petrol) tanks

slings and rope used in climbing gear

machine parts, such as gears and bearings

parachutes

metallized nylon balloons

classical and flamenco guitar strings

paintball marker bolts

racquetball, squash, and tennis racquet strings

Strings for String instruments

Drumstick heads

As filter media in sterlizing grade filters

Flexible tubing

Basketball netting